Aqua[N-(2,5-dihydroxybenzyl)imino-diacetato]copper(II).

Acta Crystallogr Sect E Struct Rep Online

Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Chemical Engineering of Guangxi Normal University, Guilin 541004, People's Republic of China.

Published: October 2009

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Article Abstract

The title complex, [Cu(C(11)H(11)NO(6))(H(2)O)], contains a Cu(II) atom in a distorted square-pyramidal geometry. The metal centre is coordinated in the basal sites by one water mol-ecule and two carboxyl-ate O atoms and one N atom of the tetra-dentate ligand [Cu-O range, 1.9376 (11)-1.9541 (12), Cu-N, 1.9929 (12) Å] while the apical site is occupied by a hydro-quinone O donor atom [Cu-O, 2.3746 (12) Å]. Inter-molecular hydrogen bonding inter-actions involving both hydro-quinone hydr-oxy groups and the coordinated water as donors give a three-dimensional framework structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971235PMC
http://dx.doi.org/10.1107/S1600536809042238DOI Listing

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