Piperazine-1,4-diium bis-[tetra-chlorido-aurate(III)] dihydrate.

Acta Crystallogr Sect E Struct Rep Online

Institute of Chemistry FEB RAS, 159 Prospekt Stoletiya, Vladivostok 690022, Russian Federation.

Published: October 2009

In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds results in the formation of a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971124PMC
http://dx.doi.org/10.1107/S1600536809041063DOI Listing

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