In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra-molecular hydrogen bonding is observed between a C-H group of the triphenyl-phosphine unit and the O atom of the enamino-ketonate ligand.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971050 | PMC |
| http://dx.doi.org/10.1107/S1600536809039816 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
1-Eth-oxy-3-[4-(eth-oxy-carbon-yl)phen-yl]-3-hy-droxy-1-oxopropan-2-aminium chloride.
IUCrdata
October 2024
University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.
The title compound, CHNO ·Cl, was prepared as a racemate of ,- and ,-enanti-omers by reduction of the corresponding hy-droxy-imino-ketone. In the crystal, layers are formed hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected inter-digitated benzoic ester groups.
View Article and Find Full Text PDFMethyl 2-[()-5-methyl-2-oxoindolin-3-yl-idene]hydrazinecarbodi-thio-ate.
IUCrdata
October 2024
EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, United Kingdom.
The title di-thio-carbazate imine, CHNOS, was obtained from the condensation reaction of -methyl-dithio-carbazate (SMDTC) and 5-methyl-isatin. It shows a configuration about the imine C=N bond, which is associated with an intra-molecular N-H⋯O hydrogen bond that closes an (6) ring. In the crystal, inversion dimers linked by pairwise N-H⋯O hydrogen bonds generate (8) loops.
View Article and Find Full Text PDFMethyl -{(1)-2-[(meth-oxy-carbon-yl)-oxy]-1-phenyleth-yl}carbamate.
IUCrdata
March 2024
Instituto de Física Luis Rivera Terrazas, Benemérita Universidad Autónoma de Puebla, 72570 Puebla, Pue., Mexico.
The title mol-ecule, CHNO, is a methyl carbamate derivative obtained by reacting ()-2-phenyl-glycinol and methyl chloro-formate, with calcium hydroxide as heterogeneous catalyst. Supra-molecular chains are formed in the [100] direction, based on N-H⋯O hydrogen bonds between the amide and carboxyl-ate groups. These chains weakly inter-act in the crystal, and the phenyl rings do not display significant π-π inter-actions.
View Article and Find Full Text PDF,'-[1,4-Phenyl-enebis(imino-carbon-yl)]bis-(l-phenyl-alanine) tetra-hydro-furan disolvate.
IUCrdata
September 2023
Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Strasse 29, 09599 Freiberg, Germany.
The title compound, CHNO·2CHO, representing a bis-urea with terminal phenyl-alanine units, crystallized with two tetra-hydro-furan (THF) mol-ecules. The main mol-ecule is located on a crystallographic twofold axis, while the solvent mol-ecule is disordered over two positions, with occupancies of 0.571 (15) and 0.
View Article and Find Full Text PDF2,6-Di-bromo-3,4,5-tri-meth-oxy-benzoic acid.
Acta Crystallogr E Crystallogr Commun
October 2023
Faculty of Pharmacy, Department of Pharmaceutical Chemistry, Medical University "Prof. Dr. Paraskev Stoyanov" Varna, 84 "Tzar Osvoboditel" Blvd., 9000 Varna, Bulgaria.
The title compound, 2,6-di-bromo-3,4,5-tri-meth-oxy-benzoic acid (DBrTMBA), CHBrO, was obtained by bromination and transhalogenation of 2-iodo-3,4,5-tri-meth-oxy-benzoic acid with KBrO. Like the previously reported 2,6-di-iodo-3,4,5-tri-meth-oxy-benzoic acid (DITMBA), the structure of the title compound features a catemeric arrangement of DBrTMBA mol-ecules along an endless chain of carb-oxy-lic H-carbonyl inter-actions. A short carbon-yl-phenyl contact hints at a possible lone pair(O)-π-hole inter-action further stabilizing the chain-like structure over a dimeric arrangement of the carb-oxy-lic acid.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!