catena-Poly[[triphenyl-tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κO:O].

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Published: October 2009

In the title polymeric coordination compound, [Sn(C(6)H(5))(3)(C(9)H(8)N(3)O(3))](n), the Sn(IV) atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2-(2-picolinoylhydrazono)propanoate ligand through one carbonyl O atom and one carboxyl-ate O atom, forming a chain structure propagating parallel to [100]. An intra-molecular N-H⋯O hydrogen bond is observed.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971240PMC
http://dx.doi.org/10.1107/S1600536809039981DOI Listing

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