N,N-Bis-(2,6-di-methyl-phen-yl)-N-hydroxyformamidine N,N'-bis-(2,6-dimethyl-phen-yl)-N-oxidoformamidinium dichloro-methane solvate.

Acta Crystallogr Sect E Struct Rep Online

Département de Chimie, Université de Montréal, CP 6128, Succ. Centre-ville, Montréal, Québec, Canada H3C 3J7.

Published: September 2009

The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy-benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy-amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O-H⋯O and N-H⋯N hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970452PMC
http://dx.doi.org/10.1107/S1600536809036708DOI Listing

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