4-Bromo-3-methyl-anilinium perchlorate.

Acta Crystallogr Sect E Struct Rep Online

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

Published: September 2009

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Article Abstract

In the title compound, C(7)H(9)BrN(+)·ClO(4) (-), the cations and anions are linked by inter-molecular N-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the ab plane.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970490PMC
http://dx.doi.org/10.1107/S160053680903520XDOI Listing

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4-Bromo-3-methyl-anilinium perchlorate 18-crown-6 clathrate.

Acta Crystallogr Sect E Struct Rep Online

February 2011

Ordered Matter Science Research Center, College of Chemistry and Chemical, Engineering, Southeast University, Nanjing 211189, People's Republic of China.

The reaction of 4-bromo-3-methyl-anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (-)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl-amine unit contains one -NH(3) (+) substituent, resulting in a 1:1 supra-molecular rotator-stator structure, (C(7)H(9)Br-NH(3) (+))(18-crown-6), through three bifurcated N-H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol-ecule.

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4-Bromo-3-methyl-anilinium perchlorate.

Acta Crystallogr Sect E Struct Rep Online

September 2009

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

In the title compound, C(7)H(9)BrN(+)·ClO(4) (-), the cations and anions are linked by inter-molecular N-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the ab plane.

View Article and Find Full Text PDF

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