[3-Bromo-2-(3-fluoro-benz-yloxy)phen-yl]boronic acid.

Acta Crystallogr Sect E Struct Rep Online

Physical Chemistry Department, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland.

Published: August 2009

In the title compound, C(13)H(11)BBrFO(3), the dioxy-boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra-molecular O-H⋯O hydrogen-bonding inter-action. The second OH group is involved in inter-molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969934PMC
http://dx.doi.org/10.1107/S1600536809033376DOI Listing

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