The asymmetric unit of the title compound, C(10)H(10)O(4), which has been isolated from rhizoma Polygonum Cuspidatum, a Chinese folk medicine, contains two crystallographically independent mol-ecules. The mol-ecules are essentially planar, with a maximum deviation of 0.061 (2) Å from the best planes. The crystal packing is stabilized by weak inter-molecular C-H⋯O hydrogen-bonding inter-actions, with a stacking direction of the mol-ecules parallel to [101].
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http://dx.doi.org/10.1107/S1600536809031183 | DOI Listing |
Cell Rep
January 2025
Institute of Microbiology, ETH Zürich, Vladimir-Prelog-Weg 4, 8093 Zürich, Switzerland. Electronic address:
How a single, naive T cell can give rise to diverse progenies of effector and memory cells is not completely understood. One way to achieve this is by asymmetric cell division (ACD), characterized by an unequal distribution of cellular cargo, resulting in divergent daughter cells already after the first division-one being more destined to an effector and the other more to a memory fate. Here, we established two methods to analyze the relative distribution of the older "mother" centrosome and the younger "daughter" centrosome during the first cell division of activated CD8 T cells.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China.
Functional fibrous membranes with high mechanical properties are intensively developed for different application fields. In this study, to enhance moisture and air permeability without compromising mechanical strength, a facile float-surface modification strategy is employed to fabricate Janus fibrous membranes with distinct hydrophobicity/hydrophilicity using the high-density polyethylene (HDPE) fibrous membranes. By coating one side of the HDPE fibrous membranes with polydopamine (PDA) and a superhydrophilic polyelectrolyte, the obtained Janus HDPE fibrous membranes demonstrate an excellent water transmission rate (577.
View Article and Find Full Text PDFNatl Sci Rev
January 2025
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China.
Lattice thermal conductivity ( ) is of great importance in basic sciences and in energy conversion applications. However, low- crystalline materials have only been obtained from heavy elements, which typically exhibit poor stability and possible toxicity. Thus, low- materials composed of light elements should be explored.
View Article and Find Full Text PDFNatl Sci Rev
January 2025
CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
In the face of advancements in microrobotics, intelligent control and precision medicine, artificial muscle actuation systems must meet demands for precise control, high stability, environmental adaptability and high integration miniaturization. Carbon materials, being lightweight, strong and highly conductive and flexible, show great potential for artificial muscles. Inspired by the butterfly's proboscis, we have developed a carbon-based artificial muscle, hydrogen-substituted graphdiyne muscle (HsGDY-M), fabricated efficiently using an emerging hydrogen-substituted graphdiyne (HsGDY) film with an asymmetrical surface structure.
View Article and Find Full Text PDFComprehensive global proteome profiling that is amenable to high throughput processing will broaden our understanding of complex biological systems. Here, we evaluated two leading mass spectrometry techniques, Data Independent Acquisition (DIA) and Tandem Mass Tagging (TMT), for extensive protein abundance profiling. DIA provides label-free quantification with a broad dynamic range, while TMT enables multiplexed analysis using isobaric tags for efficient cross-sample comparisons.
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