The mol-ecule of the title compound, C(16)H(17)N(3)O(5)S, crystallizes in a zwitterionic form, with a strong intra-molecular N-H⋯O hydrogen bond. The dihedral angle between the two benzene rings is 7.06 (9)°. In the crystal, mol-ecules are linked into chains along the c axis by inter-molecular N-H⋯O hydrogen bonds.
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http://dx.doi.org/10.1107/S1600536809031481 | DOI Listing |
Chemistry
January 2025
IIT Kharagpur: Indian Institute of Technology Kharagpur, Dept of Chemistry, IIT Kharagpur, 721302, Kharagpur, INDIA.
Although metal organic frameworks (MOFs) and covalent organic frameworks (COFs) have been extensively used as fluorescent-based antibiotic sensors, newly developed hydrogen-bonded organic frameworks (HOFs) are largely unexplored toward this direction. To realize this, the luminescent HOFs must be stable in water as the analytes are mostly found in water-based effluents in environments. In addition, HOFs should be equipped with specific recognition sites in order to direct the discrimination among the antibiotics.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China.
Various glassy hydrogels are developed by forming dense physical associations within the matrices, which exhibit forced elastic deformation and possess high stiffness, strength, and toughness. Here, the viscoplastic behaviors of the glassy hydrogel of poly(methacrylamide--methacrylic acid) are investigated by stress relaxation and creep measurements. We found that the characteristic time of stress relaxation of the glassy gel is much smaller than that of amorphous polymers.
View Article and Find Full Text PDFNanomicro Lett
January 2025
Department of Chemical Engineering and Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC-HTCM), King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia.
Transition metal carbides, known as MXenes, particularly TiCT, have been extensively explored as promising materials for electrochemical reactions. However, transition metal carbonitride MXenes with high nitrogen content for electrochemical reactions are rarely reported. In this work, transition metal carbonitride MXenes incorporated with Pt-based electrocatalysts, ranging from single atoms to sub-nanometer dimensions, are explored for hydrogen evolution reaction (HER).
View Article and Find Full Text PDFEJNMMI Radiopharm Chem
January 2025
Department of Advanced Nuclear Medicine Sciences, Institute of Quantum Medical Science, National Institutes for Quantum Science and Technology, 4-9-1 Anagawa, Inage-ku, Chiba, 263-8555, Japan.
Background: 4-(4-Cyanophenyl)-2-(2-cyclopentylidenehydrazinyl)thiazole (remodelin) is a potent N-acetyltransferase 10 (NAT10) inhibitor. This compound inhibits tumors and weakens tumor resistance to antitumor drugs. Moreover, remodelin has been found to enhance healthspan in an animal model of the human accelerated ageing syndrome.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211, P. R. China.
Photoelectrochemical (PEC) water splitting for hydrogen production is a promising technology for sustainable energy generation. In this work, we introduce Nd sites boost the PEC performance of FeO photoanodes through a precise gas-phase cation exchange process, which substitutes surface Fe atoms with Nd. The incorporation of Nd significantly enhances charge transfer properties, increases carrier concentration, and reduces internal resistance, leading to a substantial increase in photocurrent density from 0.
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