In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr-O coordination from tetra-dentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water mol-ecule occupying space in small voids and being secured by O-H⋯O hydrogen bonding as an acceptor from ligand water H atoms and as a donor to oxalate O-acceptor sites.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969896 | PMC |
| http://dx.doi.org/10.1107/S1600536809033947 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Photoinduced formation of a platina-α-lactone - a carbon dioxide complex of platinum. Insights from femtosecond mid-infrared spectroscopy.
Phys Chem Chem Phys
January 2025
Abteilung für Molekulare Physikalische Chemie, Clausius-Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Wegelerstraße 12, 53115 Bonn, Germany.
The binding of carbon dioxide to a transition metal is a complex phenomenon that involves a major redistribution of electron density between the metal center and the triatomic ligand. The chemical reduction of the ligand reveals itself unambiguously by an angular distortion of the CO-molecule as a result of the occupation of an anti-bonding π-orbital and a shift of its antisymmetric stretching vibration, ν, to lower wavenumbers. Here, we generate a carbon dioxide complex of the heavier group-10 metal, platinum, by ultrafast electronic excitation and cleavage of CO from the photolabile oxalate precursor, oxaliplatin, and monitored the ensuing primary dynamics with ultrafast mid-infrared spectroscopy.
View Article and Find Full Text PDFMagnetocaloric Effect in 3D Gd(III)-Oxalate Coordination Framework.
Nanomaterials (Basel)
December 2024
Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, School of Materials Science and Engineering, Institutes of Physical Science and Information Technology, Anhui University, Hefei 230601, China.
Cryogenic magnetic refrigerants based on the magnetocaloric effect (MCE) hold significant potential as substitutes for the expensive and scarce He-3. Gd(III)-based complexes are considered excellent candidates for low-temperature magnetic refrigerants. We have synthesized a series of Ln(III)-based metal-organic framework (MOF) (Ln = Gd/Dy) by the slow release of oxalates in situ from organic ligands (disodium edetate dehydrate (EDTA-2Na) and thiodiglycolic acid).
View Article and Find Full Text PDFUnlocking CO Activation With a Novel Ni-Hg-Ni Trinuclear Complex.
Angew Chem Int Ed Engl
January 2025
Département de chimie, Université de Montréal, Montréal, Québec, Canada, H3C 3J7.
Compounds featuring bonds between mercury and transition metals are of interest for their intriguing/ambiguous bonding and scarcely explored reactivities. We report herein the synthesis and reactivities of the new compound [(POCOP)Ni]Hg, [NiHg], featuring a trinuclear Ni-Hg-Ni core (POCOP=κ,κ,κ-2,6-(i-PrPO)CH). [NiHg] reacts with CO to give the carbonate-bridged complex [NiCO].
View Article and Find Full Text PDFSelenium-assisted copper-catalyzed synthesis of phosphoramide from secondary phosphine oxide involving the construction of N-P bonds.
Org Biomol Chem
January 2025
College of Chemical Engineering, Sichuan University of Science & Engineering, Zigong 643000, China.
In this study, phosphoramide compounds were successfully synthesized a series of reaction transformations from P(O)H compounds. The process began with the formation of P-Se-Ar bonds, facilitated by the synergistic effect of phenylboronic acid, selenium, and appropriate ligands in the presence of copper. Following this, nucleophilic substitution reactions with amine compounds were conducted to create P-N bonds.
View Article and Find Full Text PDFProlyl hydroxylase domain inhibitors prevent kidney crystal formation by suppressing inflammation.
Urolithiasis
December 2024
Department of Nephro-urology, Nagoya City University Graduate School of Medical Sciences, 1, Kawasumi, Mizuho-cho, Mizuho-ku, Nagoya, Japan.
The early stages of kidney crystal formation involve inflammation and hypoxia-induced cell injury; however, the role of the hypoxic response in kidney crystal formation remains unclear. This study investigated the effects of a prolyl hydroxylase domain inhibitor (roxadustat) on renal calcium oxalate (CaOx) crystal formation through in vitro and in vivo approaches. In the in vitro experiment, murine renal tubular cells (RTCs) were exposed to varying roxadustat concentrations and CaOx crystals.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!