Bis[N'-(3-cyano-benzyl-idene)isonicotino-hydrazide]silver(I) trifluoro-acetate.

Acta Crystallogr Sect E Struct Rep Online

College of Sciences, Henan Agricultural University, Zhengzhou 450002, People's Republic of China.

Published: August 2009

In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)CO(2), the Ag(I) ion is coordinated by two N atoms of the pyridine rings of two N'-(3-cyano-benzyl-idene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag⋯N inter-actions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related mol-ecules and inter-molecular N-H⋯O hydrogen bonds between CF(3)CO(2) (-) anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O inter-actions with a separation of 2.765 (2) Å between chains. The F atoms of the CF(3)CO(2) (-) anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5).

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970130PMC
http://dx.doi.org/10.1107/S1600536809029183DOI Listing

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