AI Article Synopsis
- The compound is made up of a magnesium ion coordinated with two 1,10-phenanthroline ligands and water molecules, arranged in a distorted octahedral shape.
- The structure features a twofold rotation symmetry axis, indicating a specific geometric arrangement of cations and anions.
- Intermolecular interactions, including hydrogen bonds and π-π stacking between aromatic rings, contribute to the compact formation of a hydrogen-bonded cluster involving the cation, anion, and solvent molecules.
Article Abstract
In the title compound, [Mg(C(12)H(8)N(2))(2)(H(2)O)(2)][Cr(2)O(7)]·2C(12)H(8)N(2), the cation and anion are situated on a twofold rotation axis. The Mg(II) ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water mol-ecules in a distorted octa-hedral geometry. Inter-molecular O-H⋯N and O-H⋯O hydrogen bonds and π-π inter-actions between the aromatic rings [shortest centroid-centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent mol-ecules into a hydrogen-bonded cluster.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969879 | PMC |
| http://dx.doi.org/10.1107/S1600536809030128 | DOI Listing |
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