Dicaesium bis-muth(III) phosphate(V) tungstate(VI), Cs(2)Bi(PO(4))(WO(4)), has been synthesized during complex investigation in a molten pseudo-quaternary Cs(2)O-Bi(2)O(3)-P(2)O(5)-WO(3) system. It is isotypic with K(2)Bi(PO(4))(WO(4)). The three-dimensional framework is built up from [Bi(PO(4))(WO(4))] nets, which are organized by adhesion of [BiPO(4)] layers and [WO(4)] tetra-hedra above and below of those layers. The inter-stitial space is occupied by Cs atoms. Bi, W and P atoms lie on crystallographic twofold axes.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970136 | PMC |
| http://dx.doi.org/10.1107/S160053680903147X | DOI Listing |
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