This paper examines the simultaneous sorption and biodegradation performance of tetracycline (TC) by the nitrifying granular sludge as well as the short-term exposure toxicity of TC. The removal of TC was characterized by a quick sorption and a slow process of biodegradation. The adsorption process fits pseudo-second-order kinetic model, with a complex mechanism of surface adsorption and intra-particle diffusion. Both temperature and mixed liquor suspended solid (MLSS) influenced TC sorption to the granules. TC biodegradation was enhanced with the increase of COD and NH(4)(+)-N concentrations, with except of the NH(4)(+)-N concentrations higher than 150 mg/L. With the ATU addition, TC degradation was weakened remarkably, indicating a synergistic effect of multiple microbes. Results of the short-term exposure (12h) effects showed that the respirometric activities of the microbes decreased greatly. The addition of TC also decreased the rate of NH(4)(+)-N utilization considerably, with the half saturation constant (K(s)) increasing from 297.7 to 347.2 mg/L.
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http://dx.doi.org/10.1016/j.jhazmat.2011.04.048 | DOI Listing |
Polymers (Basel)
December 2024
Department of Chemistry and Chemical Technology, M.Kh. Dulaty Taraz University, Taraz 080000, Kazakhstan.
This review presents a comprehensive review of cellulose-chitosan-based biocomposites that have high potential as sustainable alternatives to synthetic polymers. These biocomposites, due to biocompatibility, biodegradability, and antimicrobial properties, attract attention for wide application in various industries. This review includes modern methods for producing cellulose-chitosan composites aimed at improving their mechanical and chemical properties, such as strength, flexibility, and water resistance.
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January 2025
Department of Civil, Geological and Environmental Engineering, University of Saskatchewan, 57 Campus Dr, Saskatoon, Saskatchewan S7N 5A9, Canada; University of Lethbridge, Office of the Vice President (Research), Lethbridge, Alberta, Canada. Electronic address:
Naphthenic acids and naphthenic acid fraction compounds (NAFCs) are associated with production of unconventional petroleum resources, especially the Athabasca Oil Sands of Alberta, Canada. This complex mixture of acidic organic compounds is toxic to a variety of taxa, and so represents an important environmental management challenge. Thus, there is clear motivation to better understand the occurrence and characteristics of NAFCs in aquatic environments, their chemical behaviour, and environmental fate.
View Article and Find Full Text PDFMolecules
December 2024
Department of Chemistry, Biology and Ecology, Central Asian Innovation University, Shymkent 160000, Kazakhstan.
Cellulose-based sorbents are promising materials for wastewater treatment due to their environmental friendliness, biodegradability, and high sorption capacity. This paper presents an overview of cellulose modification methods, including carboxylation, amination, oxidation, graphene, and plasma treatments, as well as combined approaches. Their effect on key physicochemical properties, such as porosity, morphology, and chemical stability, is considered.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Beijing Key Laboratory of Farmland Soil Pollution Prevention and Remediation, College of Resources and Environmental Sciences, China Agricultural University, Beijing, 100193, China.
Microplastic pollution in terrestrial ecosystems threatens to destabilize large soil carbon stocks that help to mitigate climate change. Carbon-based substrates can release from microplastics and contribute to terrestrial carbon pools, but how these emerging organic compounds influence carbon mineralization and sequestration remains unknown. Here, microcosm experiments are conducted to determine the bioavailability of microplastic-derived dissolved organic matter (MP-DOM) in soils and its contribution to mineral-associated carbon pool.
View Article and Find Full Text PDFArch Environ Contam Toxicol
December 2024
ExxonMobil Biomedical Sciences, Inc., 1545 US Highway 22 East, Annandale, NJ, 08801-3059, USA.
Environmental risk assessments of very hydrophobic organic compounds (VHOCs) in soils are often difficult because multiple processes (e.g., sorption, volatilization, biodegradation) can complicate the interpretation of results.
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