Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4].

Dalton Trans

Department of Chemistry, 80 St. George St., University of Toronto, Toronto, Ontario, Canada M5S 3H6.

Published: June 2011

AI Article Synopsis

  • The study focuses on the synthesis of ZnMe complexes using bis-ferrocenyl-β-diketiminate ligands.
  • The reactions with the compound [Ph(3)C][B(C(6)F(5))(4)] produce two new salts.
  • These salts result from processes called electrophilic substitution and hydride abstraction, indicating the complexity and reactivity of the synthesized complexes.

Article Abstract

The ZnMe complexes of bis-ferrocenyl-β-diketiminate ligands are prepared and the reactions with [Ph(3)C][B(C(6)F(5))(4)] are found to yield the salts [H(Ph(3)C)C(MeC(N(C(5)H(4))FeCp)(2)ZnMe] [B(C(6)F(5))(4)] and [CH(2)=C(MeC(N(C(5)H(4))FeCp)(2)ZnMe][B(C(6)F(5))(4)], derived from electrophilic substitution and hydride abstraction.

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http://dx.doi.org/10.1039/c1dt10452gDOI Listing

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