A new polyhedral oligomeric silsesquioxane macromer, octakis[N-(6-aminopyridin-2-yl)undecanamide-10-dimethyl-siloxy]silsesquioxane (POSS-C11-Py), containing eight diaminopyridine arms, is able to self-assemble to form a physically crosslinked polymer-like structure with good mechanical properties (tensile strength = 46.1 MPa, tensile modulus = 0.58 GPa, elongation = 49.3%) through quadruple hydrogen bonding interactions between these arms. POSS-C11-Py is the first organic/inorganic supermolecule possessing polymer-like mechanical properties as a result of self-complementary interactions, providing a potential route toward the design and fabrication of polymer-like supramolecular materials.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/marc.201100167 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Half-Metallic Antiferromagnetic 2D Nonlayered CrSe Nanosheets.
ACS Nano
December 2024
SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 16419, Republic of Korea.
Half-metallic magnetism, characterized by metallic behavior in one spin direction and semiconducting or insulating behavior in the opposite spin direction, is an intriguing and highly useful physical property for advanced spintronics because it allows for the complete realization of 100% spin-polarized current. Particularly, half-metallic antiferromagnetism is recognized as an excellent candidate for the development of highly efficient spintronic devices due to its zero net magnetic moment combined with 100% spin polarization, which results in lower energy losses and eliminates stray magnetic fields compared to half-metallic ferromagnets. However, the synthesis and characterization of half-metallic antiferromagnets have not been reported until now as the theoretically proposed materials require a delicate and challenging approach to fabricate such complex compounds.
View Article and Find Full Text PDFSulfonated Styrene-Grafted Polyvinylidene Fluoride Copolymers for Proton Exchange Membranes for AQDS/Bromine Redox Flow Batteries.
Macromol Rapid Commun
December 2024
Department of Chemistry and Industrial Chemistry, University of Pisa, Pisa, 56124, Italy.
This study presents the preparation and electrochemical testing of sulfonated styrene-grafted poly(vinylidene fluoride) (pVDF) copolymers as proton exchange membranes (PEMs) for semi-organic redox flow batteries (RFBs) based on 9,10-anthraquinone-2,7-disulfonic acid (AQDS)/bromine. The copolymers are synthesized via a two-step procedure, involving i) atom transfer radical polymerization of styrene (Sty) for the grafting to the pVDF backbone and ii) the sulfonation of the polystyrene grafted side chains. Copolymers with different amounts of sulfonated styrene (SSty) in the side chains (i.
View Article and Find Full Text PDFInvestigations on mineralogical characteristics and feasibility of coal gangue as a concrete aggregate from guizhou province, China.
Sci Rep
December 2024
Mining College, Guizhou University, Guiyang, 550025, China.
Coal gangue (CG) is an industrial solid waste produced by coal mining and separation that is considered to have a significant effect on the soil or water environment when exposed to the air, exacerbating ecological pollution. The comprehensive utilization of CG has always been a difficult problem due to the complex mineralogical characteristics. Producing concrete aggregates with CG is an effective strategy for utilising CG resources synthetically.
View Article and Find Full Text PDFEvolution of hydraulic property and crack propagation of mine roof strata during bending-splitting deformation.
Sci Rep
December 2024
School of Resources & Safety Engineering, Central South University, Changsha, 410083, Hunan, China.
To explore the mechanism of water inrush from the mine roof strata, a series of seepage-acoustic emission (SAE) experiments on red sandstone disc samples were carried out. The effects of the height to diameter ratio (H/D) and pore pressure on the mechanical, hydraulic and crack propagation properties of red sandstones were investigated. Test results show that, the peak load of rock samples declines with the decreasing H/D and increasing pore pressure.
View Article and Find Full Text PDFPlasma-aided direct printing of silver nanoparticle conductive structures on polydimethylsiloxane (PDMS) surfaces.
Sci Rep
December 2024
Department of Engineering, Norfolk State University, Norfolk, USA.
We report a controlled deposition process using atmospheric plasma to fabricate silver nanoparticle (AgNP) structures on polydimethylsiloxane (PDMS) substrates, essential for stretchable electronic circuits in wearable devices. This technique ensures precise printing of conductive structures using nanoparticles as precursors, while the relationship between crystallinity and plasma treatment is established through X-ray diffraction (XRD) analysis. The XRD studies provide insights into the effects of plasma parameters on the structural integrity and adhesion of AgNP patterns, enhancing our understanding of substrate stretchability and bendability.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!