A hybrid organic-inorganic chain compound of the family Mn(II)-bpa-(NCO) is presented. It contains, unusually, five different dispositions for the bpa [1,2-bis(4-pyridyl)ethane] ligand. Water molecules and free bpa ligands occupy the voids of the structure. The compound shows significant antiferromagnetic-type interactions as a consequence of different exchange pathways.
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Bisphenol A degradation by manganese oxides at circumneutral pH: Quantitative evaluation of dissolved Mn(III) species with pyrophosphate.
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Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Institute of Eco-Chongming, Fudan University, Shanghai 200062, China; Institute of Atmospheric Sciences, Fudan University, Shanghai 200438, China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China. Electronic address:
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Article Synopsis
- Bisphenol A (BPA) and its analogs (BPF, BPS, BPAF) negatively affect bone tissue by disrupting key cellular processes, particularly in human osteoblasts.
- The study focused on the impact of these chemicals on growth factors like VEGF and TGF-β1, assessing gene expression changes after exposing osteoblasts to various concentrations of these compounds.
- Results showed that most bisphenols downregulated RANKL, OPG, TGF-β1, and their receptors, suggesting they could lead to harmful molecular changes that affect bone health despite BPAF prompting some OPG expression.
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