AI Article Synopsis
- The study focuses on synthesizing cyanide-bridged complexes that integrate both a low-valent rhenium(I) and a midvalent rhenium(V) metal center.
- The process involves creating new asymmetric rhenium(V) oxo compounds through specific chemical reactions, leading to the formation of two compounds, (1) and (2).
- Ultimately, these asymmetric complexes are combined with another rhenium(I) complex to produce two μ-bridged mixed-oxidation rhenium complexes (3) and (4).
Article Abstract
A series of cyanide-bridged complexes that combine a low-valent photoacceptor rhenium(I) metal center with an electroactive midvalent rhenium(V) complex were prepared. The synthesis involved the preparation of novel asymmetric rhenium(V) oxo compounds, cis-Re(V)O(CN)(acac(2)en) (1) and cis-Re(V)O(CN)(acac(2)pn) (2), formed by reacting trans-[Re(V)O(OH(2))(acac(2)en)]Cl or trans-Re(V)O(acac(2)pn)Cl with [NBu(4)][CN]. The μ-bridged cyanide mixed-oxidation Re(V)-Re(I) complexes were prepared by incubating the asymmetric complexes, 1 or 2, with fac-[Re(I)(bipy)(CO)(3)][OTf] to yield cis-[Re(V)O(acac(2)en)(μ-CN-1κC:2κN)-fac-Re(I)(bipy)(CO)(3)][PF(6)] (3) and [cis-Re(V)O(acac(2)pn)(μ-CN-1κC:2κN)-fac-Re(I)(bipy)(CO)(3)][PF(6)] (4), respectively.
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| http://dx.doi.org/10.1021/ic2005002 | DOI Listing |
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