A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 1034
Function: getPubMedXML

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3152
Function: GetPubMedArticleOutput_2016

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Ethyl 3-oxo-2-(2-phenyl-hydrazinyl-idene)butano-ate: a re-determination. | LitMetric

The previous crystallographic studies [Wang et al. (2005 ▶). Huaxue Yanjiu16, 29-32; Wang et al. (2007 ▶). Youji Huaxue, 27, 524] of the title compound, C(12)H(14)N(2)O(3), gave only the unit-cell dimensions and an R factor with no other details available: the full structure is presented here. The eth-oxy group is disordered over two orientations with refined occupancies of 0.642 (15):0.358 (15). The nine C atoms and two N atoms of the 1-phenyl-2-(propan-2-yl-idene)hydrazine segment of the mol-ecule are close to being coplanar, with a maximum deviation of 0.0779 (14) Å for the phenyl-amino N atom and an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, pairs of C-H⋯O hydrogen bonds link mol-ecules into inverson dimers, generating R(2) (2)(16) loops.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051542PMC
http://dx.doi.org/10.1107/S1600536811002200DOI Listing

Publication Analysis

Top Keywords

ethyl 3-oxo-2-2-phenyl-hydrazinyl-idenebutano-ate
4
3-oxo-2-2-phenyl-hydrazinyl-idenebutano-ate re-determination
4
re-determination previous
4
previous crystallographic
4
crystallographic studies
4
studies [wang
4
[wang 2005
4
2005 ▶
4
▶ huaxue
4
huaxue yanjiu16
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!