In the title compound, C(15)H(14)N(2)O(4), (I), the mol-ecule lies on a twofold rotation axis which passes through the central C atom of the aliphatic chain, giving one half-mol-ecule per asymmetric unit. The structure is a monoclinic polymorph of the triclinic structure previously reported [Brito, Vallejos, Bolte & López-Rodríguez (2010). Acta Cryst. E66, o792], (II). The most obvious difference between them is the O/C/C/C-O/C/C/C torsion angle [58.2 (7)° in (I) and 173.4 (3)/70.2 (3)° in (II) for GG and TG conformations, respectively]. Another important difference is observed in the dihedral angle between the planes of the aromatic rings [86.49 (7)° for (I) and 76.4 (3)° for (II)]. The crystal structure features a weak π-π inter-action [centroid-centroid distance = 4.1397 (10)Å]; this latter kind of inter-action is not evident in the triclinic polymorph.
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http://dx.doi.org/10.1107/S1600536810054309 | DOI Listing |
Inorg Chem
December 2024
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Bldg 4, 31 Leninsky Prosp., Moscow 119071, Russian Federation.
Four new Np(V) perchlorate complexes of the composition [NpO(HO)]ClO (orthorhombic) (), [(NpO)(ClO)(HO)]ClO·HO (), [(NpO)(UO)(HO)](ClO) (), and [(NpO)Cl(HO)]ClO·2HO () have been synthesized and structurally characterized. The structure of previously known monoclinic modification of NpOClO·4HO () has been determined at 100 K. The coordination environment of Np and U atoms in compounds - is pentagonal bipyramids.
View Article and Find Full Text PDFMolecules
November 2024
School of Pharmacy, Bandung Institute of Technology, Bandung 40132, Indonesia.
Piperine (PPN) is a natural compound with an anti-inflammation effect and low solubility. Hence, some molecular modifications have improved its solid-state character, including cocrystal formation. However, the salt structure has yet to be widely studied.
View Article and Find Full Text PDFJ Chem Phys
November 2024
University of Chicago, GeoSoilEnviroCARS, Advanced Photon Source, Lemont, Illinois 60439, USA.
Up to 17 GPa, the crystalline phases of N2 are characterized by pronounced orientational disorder, whereas the higher-pressure phases of molecular N2 are ordered. This raises the question about long-term relaxation of orientational disorder within the low- to intermediate-pressure regime. Here, this question is addressed by comparing synthetic with natural, chemically pure, solid N2 that resides as inclusions in diamonds at 300 K for about 108 years at pressures up to 11 GPa.
View Article and Find Full Text PDFJ Fluoresc
October 2024
Key Laboratory for Soil Modification and Comprehensive Utilization of Mineral Soil of Inner Mongolia Autonomous Region, Jining Normal University, Wulanchabu, 012000, China.
Two novel Tb(III) ternary complexes, [Tb(Phen)(p-BrBA)] and [TbY(Phen)(p-BrBA)], have been synthesized with p-bromobenzoic acid(p-BrBA) as the primary ligand and 1,10-phenanthroline(Phen) as the secondary ligand. The structures of these complexes are characterized by elemental analysis, IR spectroscopy, UV-vis absorption spectroscopy, thermal analysis (TGA) and single-crystal X-ray diffraction. The crystal structures of the compounds are similar because of similar radii of Tb ion and Y ion.
View Article and Find Full Text PDFChemistry
December 2024
Department for General, Inorganic, and Theoretical Chemistry, University of Innsbruck, Innrain 80-82, 6020, Innsbruck, Tyrol, Austria.
A hitherto unknown modification of IO was obtained from high-pressure/high-temperature syntheses in a Walker-type multianvil device at 8 GPa and 250 °C. HP-IO crystallizes in the monoclinic crystal system with space group P2/c (no. 14) with the unit cell parameters a=12.
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