AI Article Synopsis
- The title compound features two similar molecules in its asymmetric unit, each containing a Sn(IV) atom coordinated by O, N, and S from a specific ligand and two carbon atoms from phenyl rings.
- The Sn(IV) atoms display a distorted trigonal-bipyramidal geometry in their structure.
- Weak hydrogen bonds and close S⋯S contacts help organize the molecules into a centrosymmetric tetramer within the crystal packing.
Article Abstract
The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol-ecules with almost identical configurations. In each mol-ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph-thaldehyde)-thio-semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal-bipyramidal geometry. Weak inter-molecular N-H⋯O and N-H⋯S hydrogen bonds link four mol-ecules into a centrosymmetric tetra-mer. The crystal packing exhibits short inter-molecular S⋯S contacts of 3.335 (3) Å.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051660 | PMC |
| http://dx.doi.org/10.1107/S1600536810054024 | DOI Listing |
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