In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N',N''-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050264PMC
http://dx.doi.org/10.1107/S1600536810053262DOI Listing

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