Theere are two independent mol-ecules in the asymmetric unit of the title compound, C(14)H(11)FN(2)O(2), each with a trans configuration with respect to the azo double bond. The dihedral angle between the aromatic rings is 17.21 (2)° in one mol-ecule and 19.06 (2)° in the other. Each of the independent mol-ecules has an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are stacked along [100].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051973PMC
http://dx.doi.org/10.1107/S1600536811004909DOI Listing

Publication Analysis

Top Keywords

independent mol-ecules
8
1-{5-[e-2-fluoro-phen-yldiazen-yl]-2-hy-droxy-phen-yl}ethanone theere
4
theere independent
4
mol-ecules asymmetric
4
asymmetric unit
4
unit title
4
title compound
4
compound c14h11fn2o2
4
c14h11fn2o2 trans
4
trans configuration
4

Similar Publications

The mol-ecule of the title compound, [Ni(CHO)(CHN)(HO)]·CHOH, has triclinic () symmetry. This compound is of inter-est for its anti-microbial properties. The asymmetric unit comprises two independent complex mol-ecules, which are linked by N-H⋯O and O-H⋯O hydrogen bonds along [111].

View Article and Find Full Text PDF

Synthesis, crystal structure and properties of μ-tetra-thio-anti-monato-bis-[(cyclam)zinc(II)] perchlorate 0.8-hydrate.

Acta Crystallogr E Crystallogr Commun

October 2024

Institut für Anorganische Chemie, Universität Kiel, Max-Eyth.-Str. 2, D-24118 Kiel, Germany.

The reaction of Zn(ClO)·6HO with NaSbS·9HO in a water/aceto-nitrile mixture leads to the formation of the title compound, (μ-tetra-thio-anti-monato-κ :')bis-[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ )zinc(II)] perchlorate 0.8-hydrate, [Zn(SbS)(CHN)]ClO·0.8HO or [(Zn-cyclam)(SbS)][ClO]·0.

View Article and Find Full Text PDF

2-Amino-5-oxo-4-(thio-phen-2-yl)-5,6,7,8-tetra-hydro-4-chromene-3-carbo-nitrile.

IUCrdata

November 2024

School of Chemistry and Physics, University of KwaZulu-Natal, Westville campus, Private bag X54001, Durban, 4000, South Africa.

The crystal structure of the title compound, CHNOS, reveals two symmetrically independent mol-ecules within the asymmetric unit. Each mol-ecule contains a chromenone core attached to a 2-thio-phene ring, cyano, and amino groups. The 2-thio-phene ring of one of the two mol-ecules in the asymmetric unit was found to be disordered over two positions, with the major component having a site occupancy factor of 0.

View Article and Find Full Text PDF

Reaction of copper(I)chloride with 2,3-di-methyl-pyrazine in ethanol leads to the formation of the title compound, poly[[μ-chlorido-μ-(2,3-di-methyl-pyrazine)-copper(I)] ethanol hemisolvate], {[CuCl(CHN)]·0.5CHOH} or CuCl(2,3-di-methyl-pyrazine) ethanol hemisolvate. Its asymmetric unit consists of two crystallographically independent copper cations, two chloride anions and two 2,3-di-methyl-pyrazine ligands as well as one ethanol solvate mol-ecule in general positions.

View Article and Find Full Text PDF

A new triazole-based -heterocyclic carbene Ir cationic complex with a tetra-fluorido-borate counter-anion and hemi-solvating di-chloro-methane, [Ir(CH)(CHN)(CHP)]BF·0.5CHCl, has been synthesized and structurally characterized. There are two independent ion pairs in the asymmetric unit and one di-chloro-methane solvent mol-ecule per two ion pairs.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!