In the centrosymmetric dinuclear title complex, [Hg(2)Cl(4)(C(12)H(9)N(3)O(2))(2)], the Hg(II) ion is in a distorted square-pyramidal coordination environment formed by the N atoms of the diimine ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.
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http://dx.doi.org/10.1107/S1600536811004703 | DOI Listing |
Acta Crystallogr Sect E Struct Rep Online
October 2012
Department of Chemistry, Islamic Azad University, Karaj Branch, Karaj, Iran.
In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino-pyridine ligand and three Cl atoms. The benzene and pyridine rings are oriented at a dihedral angle of 56.7 (6)°.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
February 2011
In the centrosymmetric dinuclear title complex, [Hg(2)Cl(4)(C(12)H(9)N(3)O(2))(2)], the Hg(II) ion is in a distorted square-pyramidal coordination environment formed by the N atoms of the diimine ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.
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