A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Regioselective ester cleavage during the preparation of bisphosphonate methacrylate monomers. | LitMetric

Regioselective ester cleavage during the preparation of bisphosphonate methacrylate monomers.

Beilstein J Org Chem

Institut Charles Gerhardt, UMR 5253 CNRS, Ecole Nationale Supérieure de Chimie, 8, rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France.

Published: March 2011

New functional monomers bearing a methacrylate, a bisphosphonate function and, for most, an internal carboxylate group, were prepared for incorporation into copolymers with adhesive or anticorrosive properties. Methanolysis of some trimethylsilyl bisphosphonate esters not only deprotects the desired bisphosphonate function but also regioselectively cleaves the alkyl ester function without affecting the methacrylate ester.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3079116PMC
http://dx.doi.org/10.3762/bjoc.7.46DOI Listing

Publication Analysis

Top Keywords

bisphosphonate function
8
regioselective ester
4
ester cleavage
4
cleavage preparation
4
bisphosphonate
4
preparation bisphosphonate
4
bisphosphonate methacrylate
4
methacrylate monomers
4
monomers functional
4
functional monomers
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!