The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.
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| http://dx.doi.org/10.1039/c1cc11352f | DOI Listing |
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