Synthesis and isolation of {110}-faceted gold bipyramids and rhombic dodecahedra.

J Am Chem Soc

Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.

Published: April 2011

AI Article Synopsis

  • Two types of gold nanostructures, rhombic dodecahedra and obtuse triangular bipyramids, were created using a special growth method that involves silver assistance.
  • The use of a chloride-containing surfactant along with low silver ion concentration helps stabilize the unique {110} facets of these structures.
  • This research reports the first-ever successful synthesis of {110}-faceted bipyramids in the field of nanotechnology.

Article Abstract

Two {110}-faceted gold nanostructures--rhombic dodecahedra and obtuse triangular bipyramids--have been synthesized via a Ag-assisted, seed-mediated growth method. The combination of a Cl(-)-containing surfactant with a low concentration of Ag(+) plays a role in the stabilization of the {110} facets. To the best of our knowledge, this is the first reported synthesis of a {110}-faceted bipyramid structure.

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Source
http://dx.doi.org/10.1021/ja201826rDOI Listing

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