Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes.

Nat Nanotechnol

Department of Materials Science and Engineering, Materials Research Laboratory, and Beckman Institute, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

Published: May 2011

AI Article Synopsis

  • Rapid charge and discharge rates in batteries typically reduce their energy capacity, posing a challenge for energy storage solutions.
  • Supercapacitors excel in fast charge/discharge rates but have lower energy density compared to traditional batteries.
  • A new technology featuring innovative nanoarchitecture in cathodes achieves significantly high charge/discharge rates with minimal capacity loss, enabling lithium-ion batteries to charge up to 90% in just 2 minutes.

Article Abstract

Rapid charge and discharge rates have become an important feature of electrical energy storage devices, but cause dramatic reductions in the energy that can be stored or delivered by most rechargeable batteries (their energy capacity). Supercapacitors do not suffer from this problem, but are restricted to much lower stored energy per mass (energy density) than batteries. A storage technology that combines the rate performance of supercapacitors with the energy density of batteries would significantly advance portable and distributed power technology. Here, we demonstrate very large battery charge and discharge rates with minimal capacity loss by using cathodes made from a self-assembled three-dimensional bicontinuous nanoarchitecture consisting of an electrolytically active material sandwiched between rapid ion and electron transport pathways. Rates of up to 400C and 1,000C for lithium-ion and nickel-metal hydride chemistries, respectively, are achieved (where a 1C rate represents a one-hour complete charge or discharge), enabling fabrication of a lithium-ion battery that can be 90% charged in 2 minutes.

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Source
http://dx.doi.org/10.1038/nnano.2011.38DOI Listing

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