Chemical-garden formation, morphology, and composition. I. Effect of the nature of the cations.

Langmuir

Instituto Andaluz de Ciencias de la Tierra, CSIC-Universidad de Granada, Facultad de Ciencias, E-18071 Granada, Spain.

Published: April 2011

We have grown chemical gardens in different sodium silicate solutions from several metal-ion salts--calcium chloride, manganese chloride, cobalt chloride, and nickel sulfate--with cations from period 4 of the periodic table. We have studied their formation process using photography, examined the morphologies produced using scanning electron microscopy (SEM), and analyzed chemical compositions using X-ray powder diffraction (XRD) and energy dispersive X-ray analysis (EDX) to understand better the physical and chemical processes involved in the chemical-garden reaction. We have identified different growth regimes in these salts that are dependent on the concentration of silicate solution and the nature of the cations involved.

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http://dx.doi.org/10.1021/la104192yDOI Listing

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