We have grown chemical gardens in different sodium silicate solutions from several metal-ion salts--calcium chloride, manganese chloride, cobalt chloride, and nickel sulfate--with cations from period 4 of the periodic table. We have studied their formation process using photography, examined the morphologies produced using scanning electron microscopy (SEM), and analyzed chemical compositions using X-ray powder diffraction (XRD) and energy dispersive X-ray analysis (EDX) to understand better the physical and chemical processes involved in the chemical-garden reaction. We have identified different growth regimes in these salts that are dependent on the concentration of silicate solution and the nature of the cations involved.
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http://dx.doi.org/10.1021/la104192y | DOI Listing |
Nat Commun
January 2025
Department of Biochemistry, University of Zurich, Zurich, Switzerland.
Iron and manganese are essential nutrients whose transport across membranes is catalyzed by members of the SLC11 family. In humans, this protein family contains two paralogs, the ubiquitously expressed DMT1, which is involved in the uptake and distribution of Fe and Mn, and NRAMP1, which participates in the resistance against infections and nutrient recycling. Despite previous studies contributing to our mechanistic understanding of the family, the structures of human SLC11 proteins and their relationship to functional properties have remained elusive.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
Department of Neurology, the Second Affiliated Hospital, Neuroscience Research Center, Key Laboratory of Biomedical Information Engineering of Ministry of Education, School of Life Science and Technology, Xi'an Jiaotong University, Xi'an 710000, China.
Neurotransmitters and neuromodulators can be released via either action potential (AP)-evoked transient or AP-independent continuous neurotransmission. The elevated AP-evoked neurotransmission in the primary sensory neurons plays crucial roles in hyperalgesia. However, whether and how the AP-independent continuous neurotransmission contributes to hyperalgesia remains largely unknown.
View Article and Find Full Text PDFChemMedChem
January 2025
National Taiwan University, Chemistry, No.1, Sec.4, Roosevelt Road, Deptartment of Chemistry, Rm A521, 106319, Taipei, TAIWAN.
Cofactors are non-protein entities necessary for proteins to operate. They provide "functional groups" beyond those of the 20 canonical amino acids and enable proteins to carry out more diverse functions. Such a viewpoint is rarely mentioned, if at all, when it comes to natural products and is the theme of this Concept.
View Article and Find Full Text PDFSmall
January 2025
Materials Genome Institute, Shanghai University, Shanghai, 200444, China.
The local structure plays a crucial role in oxygen redox reactions, which boosts the capacity of layered oxide cathodes for sodium-ion batteries. While studies on local structural ordering have primarily focused on the intra-layer ordering, there has been limited research on the inter-layer stacking for the layered cathode materials for sodium-ion batteries. In this work, the impact of the intra-layer and inter-layer local structural regulation on anionic kinetics and the structure stability are explored through experimental analysis and theoretical calculations.
View Article and Find Full Text PDFDalton Trans
January 2025
School of Science and Technology, Nottingham Trent University, Clifton Lane, Clifton, Nottingham, NG11 8NS, UK.
This paper reports the synthesis, crystal structures and conducting properties of the first BEDT-TTF radical-cation salts with symmetry tris-coordinated racemic lanthanide(III) anions. It is also the first crystallographic determination of the nine-coordinate tris(chelidonato)terbate and tris(chelidonato)dysprosate anions (chelidonic acid = clo = 4-oxo-4-pyran-2,6-dicarboxylic acid). Salt α-(BEDT-TTF)M(chelidonato)·EtOH·2HO is semimetallic for M = Tb, and semiconducting for M = Dy.
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