Antiferro-quadrupolar structures in UPd3 inferred from x-ray resonant Bragg diffraction.

J Phys Condens Matter

European Synchrotron Radiation Facility, BP 220, 38043 Grenoble Cedex, France.

Published: January 2010

A systematic analysis of resonant x-ray Bragg diffraction data for UPd(3), with signal enhancement at the U M(IV) edge, including possible structural phase transitions leads to a new determination of the space groups of the material in the phases between T(0)=7.8 K and T(+1)=6.9 K, as P 222(1), and between T(-1)=6.7 K and T(2)=4.4 K, as P2(1). In addition, the quadrupolar order parameters, {Q(ab)}, inferred from diffraction data for the phase between T(-1) and T(2), are {Q(xz)} and {Q(yz)} at the (103) Bragg reflection and {Q(xy)} at the (104) reflection.

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http://dx.doi.org/10.1088/0953-8984/22/2/022202DOI Listing

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