A modified rectangular loop-gap resonator for X-band electron paramagnetic resonance (EPR) studies of aqueous samples, enabling the light access, is described. Changes introduced into rectangular resonator geometry, previously presented in Piasecki et al. (1998) [1], and redesigned coupling structure lead to the better thermal and mechanical stability. The modified structure makes provision for the controlled light access to the sample placed in a flat cell during an EPR experiment. The sensitivity of the resonator for aqueous samples as well as an experimentally tested microwave magnetic field homogeneity are presented. Results of simulations and experimental tests indicate that the presence of light access holes in the resonator's front side does not disturb the uniformity of microwave magnetic field distribution in the nodal plane. The optimal flat cell thickness for unsaturable and saturable aqueous samples has been calculated for this new structure. A modified rectangular geometry of the loop-gap resonator ensures a good performance for aqueous samples allowing its convenient and efficient light illumination during EPR signal recording .
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http://dx.doi.org/10.1016/j.jmr.2011.02.009 | DOI Listing |
Langmuir
December 2024
Department of Chemistry, University of Washington, Seattle, Washington 98195, United States.
Circular dichroism (CD) spectroscopy has emerged as a potent tool for probing chiral small-molecule ligand exchange on natively achiral quantum dots (QDs). In this study, we report a novel approach to identifying QD-biomolecule interactions by inducing chirality in CdS QDs using thermoresponsive elastin-like polypeptides (ELPs) engineered with C-terminal cysteine residues. Our method is based on a versatile two-step ligand exchange process starting from monodisperse oleate-capped QDs in nonpolar media and proceeding through an easily accessed achiral glycine-capped QD intermediate.
View Article and Find Full Text PDFFront Glob Womens Health
December 2024
Department of Epidemiology and Public Health, School of Life Science, Central University of Tamil Nadu, Thiruvarur, India.
Background: In low-income countries, women with disabilities face numerous challenges in accessing sexual and reproductive health services and experience high unintended pregnancy rates and adverse pregnancy outcomes, with 42% of cases ending in abortion. However, little is known about unintended pregnancy among women with disabilities in Ethiopia. Therefore, this study aimed to assess the prevalence of unintended pregnancy and associated factors among women with disabilities in the Central Regional State of Ethiopia.
View Article and Find Full Text PDFOpen Vet J
November 2024
Department of Parasitology, College of Veterinary Medicine, University of Al-Qadisiyah, Al Diwaniyahs, Iraq.
Background: is one of the most important parasites, which infests the upper respiratory tract of camels leading to deteriorating health effects, substantial economic losses, and even death.
Aim: This study aimed to detect the prevalence rate of in slaughtered camels, determining its morphology using the electron microscope, and confirming its species by molecular phylogeny.
Methods: A total of 200 slaughtered camels at different areas in Al Muthanna province (Iraq) were inspected visually to collect the parasite samples that were identified initially based on their morphological characteristics.
Health Res Policy Syst
December 2024
South African Medical Research Council, Cape Town, South Africa.
Background: Despite South Africa's well-established Civil Registration and Vital Statistics system (CRVS) and good completeness of death registration, challenges persist in terms of the quality of cause of death information and the delayed availability of mortality statistics. The introduction of an electronic medical certification of cause of death (eMCCD) system may offer opportunities to improve both the quality and timeliness of this information.
Methods: This study used an exploratory mixed methods design to investigate perceptions surrounding an electronic solution for registering deaths in South Africa.
BMC Musculoskelet Disord
December 2024
Department of Orthopedics, Hainan Hospital of PLA General Hospital, Hainan, China.
Background: Prolonged dependence on mechanical ventilation is a common occurrence in clinical ICU patients and presents significant challenges for patient care and resource allocation. Predicting prolonged dependence on mechanical ventilation is crucial for improving patient outcomes, preventing ventilator-associated complications, and guiding targeted clinical interventions. However, specific tools for predicting prolonged mechanical ventilation among ICU patients, particularly those with critical orthopaedic trauma, are currently lacking.
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