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Utilization of Chlorella vulgaris methyl ester blend with diethyl ether to mitigate emissions of an unaltered single cylinder ci engine.
Environ Sci Pollut Res Int
January 2025
Engine Testing Laboratory, Department of Automobile Engineering, College of Engineering and Technology, SRM Institute of Science and Technology, Kattankulathur, 603203, Tamil Nadu, India.
The present work emphasizes the viability of methyl ester production, characterization, and utilization of third-generation biofuel from Chlorella vulgaris microalgae. The presence of methyl oleate (CHO) in the Chlorella vulgaris methyl ester (CVME) algae signifies the existence of higher oxidation stability and prone to peroxidation. The single-stage transesterified CVME algae contains majorly (C-H) functional group trailed by (C = O), (C-O), (O-CH), (C-O-C) with the elemental compositions of 66.
View Article and Find Full Text PDFConfinement-induced Ni-based MOF formed on TiCT MXene support for enhanced capacitive deionization of chromium(VI).
Sci Rep
January 2025
School of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng, 224051, People's Republic of China.
MXenes, as a novel two-dimensional lamellar material, has attracted much attention. However, MXenes lamellar are prone to collapse and stacking under hydrogen bonding and interlayer van der Waals forces, which affects their electrochemical and capacitive deionization performance. A three-dimensional Ni-1,3,5-benzenetricarboxylate/TiCT (Ni-BTC/TiCT) composite electrode material was developed to enhance the electrochemical and capacitive deionization performance.
View Article and Find Full Text PDFNon-fullerene acceptors with high crystallinity and photoluminescence quantum yield enable >20% efficiency organic solar cells.
Nat Mater
January 2025
School of Chemistry, Beihang University, Beijing, China.
The rational design of non-fullerene acceptors (NFAs) with both high crystallinity and photoluminescence quantum yield (PLQY) is of crucial importance for achieving high-efficiency and low-energy-loss organic solar cells (OSCs). However, increasing the crystallinity of an NFA tends to decrease its PLQY, which results in a high non-radiative energy loss in OSCs. Here we demonstrate that the crystallinity and PLQY of NFAs can be fine-tuned by asymmetrically adapting the branching position of alkyl chains on the thiophene unit of the L8-BO acceptor.
View Article and Find Full Text PDFEcofriendly remediation of cadmium, lead, and zinc using dead cells of Microcystis aeruginosa.
Sci Rep
January 2025
Hydrobiology Lab, National Institute of Oceanography and Fisheries (NIOF), Cairo, Egypt.
The utilization of cyanobacteria toxin-producing blooms for metal ions adsorption has garnered significant attention over the last decade. This study investigates the efficacy of dead cells from Microcystis aeruginosa blooms, collected from agricultural drainage water reservoir, in removing of cadmium, lead, and zinc ions from aqueous solutions, and simultaneously addressing the mitigation of toxin-producing M. aeruginosa bloom.
View Article and Find Full Text PDFDiscovery of ketene/acetyl as a potential receptor for hydrogen-transfer reactions in zeolites.
Nat Commun
January 2025
School of Physical Science and Technology, ShanghaiTech University, 393 Middle Huaxia Road, Shanghai, China.
Hydrogen-transfer is the primary process responsible for elevating the degree of unsaturation of intermediates in zeolite-catalyzed methanol-to-hydrocarbon reactions, with olefins serving as the typical receptor and alkanes being produced as the by-product. Intriguingly, the introduction of CO was shown to suppress the selectivity of alkanes and enhance the production of aromatics, yet microscopic understanding of this phenomenon remains elusive. Here, based on ab initio molecular dynamics simulations and free energy sampling methods, we discover a non-olefin-induced hydrogen-transfer reaction in the presence of CO, with ketene/acetyl emerging as a more suitable hydrogen-transfer receptor than olefins.
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