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A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string.
Chem Commun (Camb)
April 2017
Department of Chemistry and Centre for Emerging Material and Advanced Devices, National Taiwan University, Taipei 106, Taiwan.
Striding to extend the length of metal-atom strings, oligo-α-pyridylamino ligands are modulated with naphthyridyl moieties leading to the undeca-nickel mixed-valence complexes [Ni(bnatpya)Cl] (1) and [Ni(bnatpya)Cl] (2). The first single-molecule conductance measurements of a linear undeca-nickel chain were performed.
View Article and Find Full Text PDFTwo linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings.
Angew Chem Int Ed Engl
February 2011
Department of Chemistry, National Taiwan University, 1, Sec. 4, Roosevelt Road, Taipei, 106, Taiwan, ROC.
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