Hollow silica nanoparticles (HSNP) with diameters comparable to visible wavelengths and with thin shells (<15 nm) feature an unexpected color effect. Single particle and powder spectroscopy, as well as calculations based on Mie theory were used to investigate this phenomenon. The use of HSNPs increases the transport mean free path of light significantly, which reduces multiple scattering, and thus the Mie resonances become visible to the bare eye.
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http://dx.doi.org/10.1021/nl2002445 | DOI Listing |
Chem Asian J
January 2025
Departamento de Química, Facultad de Ciencias, Universidad de Chile, Las Palmeras 3425, 7800003, Santiago, Chile.
Plasmonic materials can be utilized as effective platforms to enhance luminescent signals of luminescent metal nanoclusters (LMNCs). Both surface enhanced fluorescence (SEF) and shell-isolated nanoparticle-enhanced fluorescence (SHINEF) strategies take advantage of the localized and increased external electric field created around the plasmonic metal surface when excited at or near their characteristic plasmonic resonance. In this context, we present an experimental and computational study of different plasmonic composites, (Ag) Ag@SiO and (Au) Au@SiO nanoparticles, which were used to enhance the luminescent signal of Au nanoclusters coated with glutathione (GSH) molecule (AuGSH NCs).
View Article and Find Full Text PDFNanophotonics
June 2024
POLIMA-Center for Polariton-driven Light-Matter Interactions, University of Southern Denmark, Odense M, Denmark.
We discuss the possibility of self-hybridisation in high-index dielectric nanoparticles, where Mie modes of electric or magnetic type can couple to the interband transitions of the material, leading to spectral anticrossings. Starting with an idealised system described by moderately high constant permittivity with a narrow Lorentzian, in which self-hybridisation is visible for both plane-wave and electron-beam excitation, we embark on a quest for realistic systems where this effect should be visible. We explore a variety of spherical particles made of traditional semiconductors such as Si, GaAs, and GaP.
View Article and Find Full Text PDFNanophotonics
August 2024
Key Laboratory of Optoelectronic Technology & Systems, Ministry of Education, and College of Optoelectronic Engineering, Chongqing University, Chongqing 400044, China.
Interference between the electric and magnetic dipole-induced in Mie nanostructures has been widely demonstrated to tailor the scattering field, which was commonly used in optical nano-antennas, filters, and routers. The dynamic control of scattering fields based on dielectric nanostructures is interesting for fundamental research and important for practical applications. Here, it is shown theoretically that the amplitude of the electric and magnetic dipoles induced in a vanadium dioxide nanosphere can be manipulated by using laser-induced metal-insulator transitions, and it is experimentally demonstrated that the directional scattering can be controlled by simply varying the irradiances of the excitation laser.
View Article and Find Full Text PDFACS Omega
November 2024
Department of Applied Chemistry, Graduate School of Engineering, Mie University, Tsu, Mie 514-8507, Japan.
Materials (Basel)
September 2024
Institute for Technical Physics and Materials Science, HUN-REN Centre for Energy Research, Konkoly Thege Miklos út 29-33, H-1121 Budapest, Hungary.
Colloidal CuO nanoparticles can exhibit both photocatalytic activity under visible light illumination and resonant Mie scattering, but, for their practical application, they have to be immobilized on a substrate. Butterfly wings, with complex hierarchical photonic nanoarchitectures, constitute a promising substrate for the immobilization of nanoparticles and for the tuning of their optical properties. The native wax layer covering the wing scales of butterflies was removed by simple ethanol pretreatment prior to the deposition of CuO nanoparticles, which allowed reproducible deposition on the dorsal blue wing scale nanoarchitectures via drop casting.
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