This work reports a pioneer application of the bulk photovoltaic effect in the biomedical field. Massive necrotic cell death was induced in human tumour cell cultures grown on a bulk photovoltaic material (iron-doped lithium niobate, LiNbO(3):Fe) after irradiation with visible light. Lethal doses (≈100% cell death) were obtained with low-intensity visible light sources (10-100 mW cm(-2) irradiances) and short exposure times of the order of minutes. The wavelength dependence to induce the lethal effect observed is consistent with that corresponding to the bulk photovoltaic effect generation in LiNbO(3):Fe. Necrosis also occurred when cultured tumour cells were exposed to LiNbO(3):Fe microparticles and visible light.
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http://dx.doi.org/10.1039/c0pp00336k | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Chinese Academy of Sciences Fujian Institute of Research on the Structure of Matter, State Key Laboratory of Structure Chemistry, CHINA.
The discovery of ferroelectricity in two-dimensional (2D) semiconductors has opened a new and exciting chapter in next-generation electronics and spintronics due to their lattice-dimensionality-induced unique behaviors and fascinating functionalities brought by spontaneous polarization. The emerging layered halide perovskites with 2D lattices provide a great platform for generating reduced symmetry and low-dimensional ferroelectricity. Herein, inspired by the approach of reduced lattice dimensionality, a series of 2D layered germanium iodide perovskite ferroelectric semiconductors A2CsGe2I7 [where A = PA (propylammonium), BA (butylammonium) and AA (amylammonium)] was firstly developed, which demonstrates remarkable semiconducting features including narrow direct bandgap (~1.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Physics, School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China.
Two-dimensional (2D) materials with spontaneous polarization can exhibit large second-order nonlinear optical (NLO) effects. Here, we present a series of stable distorted monolayers by using first-principles calculations and lattice vibration analysis. The structural distortion leads to a lower polar symmetry, giving rise to intrinsic ferroelectricity with a Curie point up to room temperature.
View Article and Find Full Text PDFSmall
January 2025
Key Laboratory of Wide Bandgap Semiconductor Materials and Devices, School of Microelectronics, Xidian University, Xi'an, 710071, China.
The multiple exciton generation (MEG) effect, which produces multiple photo-generated charge carriers from a single high-energy photon absorption by a semiconductor with a narrow bandgap, has the potential to revolutionize photovoltaic, photoelectric detection, and other technologies. Here, this work finds that the surface carbon-modified wide-bandgap photoanode with hierarchical quantum structure can drive a photoelectrochemical reaction with a quantum efficiency exceeding 145% by the first time. More studies reveal that the presence of the MEG effect in the MEG-CdS photoanode is attributed to the formation of high-quality surface C-modified CdS quantum nanosheets on CdS bulk film by in situ, this hierarchical quantum structure leads to quantum confinement effects that increase effective Coulomb interaction for driving MEG and decrease competition for thermal exciton cooling.
View Article and Find Full Text PDFSmall
January 2025
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian, 350108, China.
Narrowband photodetection with selective light detection in ultraviolet (UV) range is particularly pronounced in specialized such as targeted wavelength imaging and UV-phototherapy. In contrast to conventional strategies, ferroelectric materials with pronounced bulk photovoltaic effect (BPVE) provide a novel asymmetric carrier generation concept for achieving filterless spectrally selective photodetection. Herein, for the first time, the realization of self-powered filterless narrowband UV photodetection is demonstrated in bulk single crystals of a newly developed halide perovskite ferroelectric, 2FEAEAPbCl (2FEEPC), which exhibits a wide bandgap of 3.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Physics, Florida State University, 612 Keen Building, Florida State University, Tallahassee, Florida, 32306, UNITED STATES.
We argue that alternating-layer structures of lattice mismatched or misaligned (twisted) atomically-thin layers should be expected to be more efficient absorbers of the broad-spectrum of solar radiation than the bulk material of each individual layer. In such mismatched layer-structures the conduction and valence bands of the bulk material, split into multiple minibands separated by minigaps confined to a small-size emerging Brillouin zone due to band-folding. We extended the Shockley-Queisser approach to calculate the photovoltaic efficiency for a band split into minibands of bandwidth $\Delta E$ and mini-gaps $\delta G$ to model the case when such structures are used as solar cells.
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