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Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles. | LitMetric
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Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles.

Yuye Li Yi Shi Zhongxing Huang Xinhu Wu Pengfei Xu Jianbo Wang Yan Zhang

Org Lett

Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing, China.

Published: March 2011

A series of 3-arylthio-1,3-disubstituted-oxindoles were prepared in good yields by the reaction of α-diazocarbonyl compounds and sulfenamides. The reaction involves a Rh-catalyzed thia-Sommelet-Hauser-type rearrangement.

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 Source
http://dx.doi.org/10.1021/ol200091kDOI Listing

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