The interaction free energy of parallel clusters of like-charged rod polyelectrolytes in solution is calculated in the framework of the extended condensation theory. For sufficiently high linear charge density of the polyelectrolyte, clustering takes place. The greater is the number of polyelectrolytes participating to the cluster, the smaller is the equilibrium interpolyelectrolyte distance, and the deeper is the corresponding free energy minimum. It is a counterintuitive organization due to the increasing of the counterion condensed charge and condensation volume, taking place as the polyelectyrolytes approach each other.
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http://dx.doi.org/10.1063/1.3533276 | DOI Listing |
Psychiatry Res
December 2024
Department of Translation and Language Sciences, Universitat Pompeu Fabra, Barcelona, Spain; Catalan Institute for Advanced Studies and Research (ICREA), Barcelona, Spain.
Narrative speech production requires the retrieval of concepts to refer to entities, which need to be referenceable more than once for any form of narrative coherence to arise. Such coherence has long been observed to be affected in schizophrenia spectrum disorders (SSD), yet the underlying mechanisms have been a longstanding puzzle, with existing evidence predominantly derived from Indo-European languages. Here we analyzed two picture descriptions from 22 native Mandarin Chinese speakers with SSD and 15 healthy controls.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Vienna Center for Quantum Science and Technology, Atominstitut, TU Wien, 1020 Vienna, Austria.
Phys Rev Lett
December 2024
Center for Soft Condensed Matter Physics and Interdisciplinary Research, Soochow University, Suzhou 215006, China.
We show that spontaneous density segregation in dense systems of aligning circle swimmers is a condensation phenomenon at odds with the phase separation scenarios usually observed in two-dimensional active matter. The condensates, which take the form of vortices or rotating polar packets, can absorb a finite fraction of the particles in the system, and keep a finite or slowly growing size as their mass increases. Our results are obtained both at particle and continuous levels.
View Article and Find Full Text PDFNat Commun
January 2025
CP3-Origins, University of Southern Denmark, Odense, Denmark.
The understanding of phenomena falling outside the Ginzburg-Landau paradigm of phase transitions represents a key challenge in condensed matter physics. A famous class of examples is constituted by the putative deconfined quantum critical points between two symmetry-broken phases in layered quantum magnets, such as pressurised SrCu(BO). Experiments find a weak first-order transition, which simulations of relevant microscopic models can reproduce.
View Article and Find Full Text PDFNat Nanotechnol
January 2025
Laboratoire de Physique de l'Ecole Normale Supérieure, Paris, France.
The world of nanoscales in fluidics is the frontier where the continuum of fluid mechanics meets the atomic, and even quantum, nature of matter. While water dynamics remains largely classical under extreme confinement, several experiments have recently reported coupling between water transport and the electronic degrees of freedom of the confining materials. This avenue prompts us to reconsider nanoscale hydrodynamic flows under the perspective of interacting excitations, akin to condensed matter frameworks.
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