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Eco-friendly synthesis of gold nanoparticles via peel extract: Unveiling their multifaceted biological and catalytic potentials.
Heliyon
January 2025
Medical Toxicology and Drug Abuse Research Center (MTDRC), Birjand University of Medical Sciences, Birjand, Iran.
Recent advancements in nanoscience underscore the transformative potential of nanomaterials in environmental and biological applications. In this study, we synthesized gold nanoparticles (Au@ NPs) using an eco-friendly and cost-effective approach, leveraging peel extract as both a capping and reducing agent. This method presents a sustainable alternative to traditional chemical agents.
View Article and Find Full Text PDFSynthesis of Mn-doped hollow octahedron ZnInS to enhance photocatalytic hydrogen production performance utilizing metal-organic framework as template.
J Colloid Interface Sci
January 2025
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061 PR China.
Designing semiconductor photocatalysts with unique structures can improve the transfer efficiency of solar energy to hydrogen (H). In this study, a dual modification method of element doping and morphological control was used. The Mn-doped hollow octahedron ZnInS (ZHO-Mn) was synthesized by a simple one-pot solvothermal method using the octahedral Mn-based metal-organic framework (Mn-MOF) as a template.
View Article and Find Full Text PDFPhotocatalytic production and biological activity of D-arabino-1,4-lactone from D-fructose.
Sci Rep
January 2025
Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-0012, Japan.
Lactones play crucial roles in various fields, such as pharmaceuticals, food, and materials science, due to their unique structures and diverse biological activities. However, certain lactones are difficult to obtain in large quantities from natural sources, necessitating their synthesis to study their properties and potential. In this study, we investigated the photocatalytic conversion of D-fructose, a biomass-derived and naturally abundant sugar, using a TiO photocatalyst under light irradiation in ambient conditions.
View Article and Find Full Text PDFCO driven tunable syngas synthesis via CO photoreduction using a novel NiCo bimetallic metal-organic frameworks.
J Colloid Interface Sci
January 2025
School of Chemistry, Sun Yat-sen University, Guangzhou 510275, Guangdong, China. Electronic address:
Syngas has important industrial applications, and converting CO to CO is critical for syngas production. Metal-organic frameworks (MOFs) have demonstrated significant potential in photocatalytic syngas conversion, although the impact of catalytic reactions on tunable H/CO ratios remains unclear. Herein, we present a novel bimetallic NiCo-MOF catalyst, NiCo, exhibiting high catalytic activity in syngas conversion due to the CO product self-driven effect.
View Article and Find Full Text PDFPhotocatalytic Direct Borylation of Benzothiazole Heterocycles via a Triplet Activation Strategy.
Org Lett
January 2025
Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, College of Chemistry & Chemical Engineering, Anhui University, Hefei, Anhui 230601, China.
Boron compounds are widely employed in organic chemistry, pharmaceuticals, and materials science. Among them, borylated heterocycles serve as versatile synthons for the construction of new C-C or C-heteroatom bonds via coupling or radical processes. Such methods for direct C-H borylation reactions are of high synthetic value to reduce the number of synthetic steps and the amount of waste and to improve efficiency.
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