Early-transition-metal catalysts with phenoxy-imine-type ligands for the oligomerization of ethylene.

Chem Asian J

Research Center, Mitsui Chemicals, Inc., 580-32 Nagaura, Sodegaura, Chiba 299-0265, Japan.

Published: February 2011

Early-transition-metal complexes incorporating phenoxy-imine-type bidentate and tridentate ligands, after activation, can achieve selective as well as nonselective ethylene oligomerization to produce 1-hexene, linear α-olefins, and vinyl-terminated low-molecular-weight polyethylenes, all with high efficiency.

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http://dx.doi.org/10.1002/asia.201000563DOI Listing

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