In this article we report a new strategy to build fused/spiro/bridged carbocyclic systems with a novel 6-C synthon from readily available diallyl diacetates through the sequential Pd-catalyzed double allyl alkylation and Diels-Alder annulation. Further exploration on the application of this strategy can construct useful complex scaffolds.
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| http://dx.doi.org/10.1039/c0ob00660b | DOI Listing |
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