It is shown that quantum fluctuation theorems remain unaffected if measurements of any kind and number of observables are performed during the action of a force protocol. That is, although the backward and forward probabilities entering the fluctuation theorems are both altered by these measurements, their ratio remains unchanged. This observation allows us to describe the measurement of fluxes through interfaces and, in this way, to bridge the gap between the current theory, based on only two measurements performed at the beginning and end of the protocol, and experiments that are based on continuous monitoring.
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http://dx.doi.org/10.1103/PhysRevLett.105.140601 | DOI Listing |
BMJ Open
January 2025
Pharmaceutics and Social Pharmacy, Addis Ababa University College of Health Sciences, Addis Ababa, Ethiopia.
Objective: This study analysed the spatial and temporal patterns of cervical cancer incidence in Addis Ababa from 2012 to 2021.
Design: An ecological study was conducted from 1 September to 30 November 2023 to examine the spatiotemporal trends of cervical cancer incidence.
Setting: The research was conducted in Addis Ababa, the capital city of Ethiopia.
ACS Photonics
January 2025
Center for Nanophotonics, AMOLF, Science Park 104, XG Amsterdam 1098, the Netherlands.
We present a complete framework of stochastic thermodynamics for a single-mode linear optical cavity driven on resonance. We first show that the steady-state intracavity field follows the equilibrium Boltzmann distribution. The effective temperature is given by the noise variance, and the equilibration rate is the dissipation rate.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
School of Ocean Sciences, Bangor University, Menai Bridge, Anglesey LL59 5AB, U.K.
Accurate prediction of chlorophyll- (Chl-) concentrations, a key indicator of eutrophication, is essential for the sustainable management of lake ecosystems. This study evaluated the performance of Kolmogorov-Arnold Networks (KANs) along with three neural network models (MLP-NN, LSTM, and GRU) and three traditional machine learning tools (RF, SVR, and GPR) for predicting time-series Chl- concentrations in large lakes. Monthly remote-sensed Chl- data derived from Aqua-MODIS spanning September 2002 to April 2024 were used.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, D-81377 Munich, Germany.
Recently, we investigated a number of so-called σ- and τ-functionals based on the adiabatic-connection fluctuation-dissipation theorem (ACFDT); particularly, extensions of the random phase approximation (RPA) with inclusion of an exchange kernel in the form of an antisymmetrized Hartree kernel. One of these functionals, based upon the approximate exchange kernel (AXK) of Bates and Furche, leads to a nonlinear contribution of the spline function used within σ-functionals, which we previously avoided through the introduction of a simplified "top-down" approach in which the σ-functional modification is inserted a posteriori following the analytic coupling strength integration within the framework of the ACFDT and which was shown to provide excellent performance for the GMTKN55 database when using hybrid PBE0 reference orbitals. In this work, we examine the analytic "bottom-up" approach in which the spline function is inserted a priori, i.
View Article and Find Full Text PDFJ Chem Phys
December 2024
School of Mathematical Sciences, Shanghai Jiao Tong University, Shanghai 200240, China.
The random batch method is advantageous in accelerating force calculations in particle simulations, but it poses a challenge of removing the artificial heating effect in application to the Langevin dynamics. We develop an approach to solve this issue by estimating the force variance, resulting in a variance-reduced random batch Langevin dynamics. Theoretical analysis shows the high-order local truncation error of the time step in the numerical discretization scheme, consistent with the fluctuation-dissipation theorem.
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