The dynamics of the discotic liquid-crystalline system, hexakis (n-hexyloxy) triphenylene (HAT6), is considered in the frame of the phenomenological model for rate processes proposed by Berlin. It describes the evolution of the system in the presence of the long-time scale correlations in the system, and we compare this with experimental quasielastic neutron scattering of the molecular assembly of HAT6 in the columnar phase. We interpret the parameters of this model in terms of nonextensive thermodynamics in which rare events in the local fast dynamics of some parts of the system control the slower dynamics of the larger molecular entity and lead to a fractional diffusion equation. The importance of these rare local events to the overall dynamics of the system is linked to the entropic index, this being obtained from the data within the model approach. Analysis of the waiting-time dependence from momentum transfer reveals a Lévy distribution of jump lengths, which allows us to construct the van Hove correlation function for discotic liquid-crystalline system.
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http://dx.doi.org/10.1103/PhysRevE.82.051703 | DOI Listing |
Polymers (Basel)
November 2024
School of Materials Science and Engineering, Key Laboratory of High Energy Density Materials (MOE), Beijing Institute of Technology, Beijing 100081, China.
Block copolymers (BCPs) have attracted considerable attention due to their ability to form a variety of complex assemblies with diverse morphologies and functions in solution. By incorporating liquid crystalline (LC) moieties, the LC side chains significantly affect the morphologies and sizes of BCP assemblies. In this study, we synthesized the copolymer with an LC block containing triphenylene (HAT) discotic mesogen and short methylene side chains.
View Article and Find Full Text PDFJ Org Chem
November 2024
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, P. R. China.
Soft Matter
October 2024
Department of Chemistry and Biochemistry, 401 Sunset Ave, Ontario N9B 3P4, Canada.
Thermotropic ionic liquid crystals have remained a relatively little studied group of materials despite their many potential applications as anisotropic ionic liquids and charge (ion and electron/hole) transporting materials. Particularly rare are core charged discotic liquid crystals because their synthesis is usually more involved, and their molecular design is less established. Presented here is a straightforward and versatile synthetic approach to imidazolium annulated triphenylene derivatives.
View Article and Find Full Text PDFLangmuir
August 2024
Department of Molecular Science and Engineering, National Taipei University of Technology, Taipei 106, Taiwan.
Films of the discotic liquid crystalline hexabenzocoronene (HBC) derivative, , were prepared on the quartz substrate by the bar-coating method. Depending on the coating speed, regularly spaced stripes or continuous films were observed. In the former case, columns of the HBC derivatives align more along the stripes, which are perpendicular to the coating direction, whereas in the latter case, columns of the HBC derivatives in the film align more along the coating direction.
View Article and Find Full Text PDFChem Asian J
September 2024
Soft Condensed Matter, Raman Research Institute, C. V. Raman Avenue, Bengaluru, 560080, India.
The incorporation of heteroatoms in the chemical structure of organic molecules has been identified as analogous to the doping process adopted in silicon semiconductors to influence the nature of charge carriers. This strategy has been an eye-opener for material chemists in synthesizing new materials for optoelectronic applications. Phenanthro[9,10-a]phenazine-based mesogens have been synthesized via a cyclo-condensation pathway involving triphenylene-based diketone and o-phenyl diamines.
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