Salen-based metal-organic frameworks of nickel and the lanthanides.

Chem Commun (Camb)

Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, 76128 Karlsruhe, Germany.

Published: February 2011

A well defined salen-nickel complex was introduced as "metalloligand" in lanthanide-based MOFs. By using this strategy unique structures, in which the salen-nickel unit acts as flexible strut, were obtained. The shape of the network is strongly influenced by the ion radius of the lanthanide element.

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Source
http://dx.doi.org/10.1039/c0cc04881jDOI Listing

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