In the mol-ecule of the title compound, C(28)H(30)N(4)O(8)S(2)·C(2)H(6)O, the benzene ring is oriented at dihedral angles of 38.50 (6) and 5.68 (5)° with respect to the trimethoxy-phenyl rings, while the two trimethoxy-phenyl rings are oriented at a dihedral angle of 44.18 (5)°. Intra-molecular N-H⋯O and N-H⋯S hydrogen bonds result in the formation of non-planar six-, seven- and eight-membered rings. The twisting modes of the two side arms are different [C-N-C-O and C-N-C-N torsion angles = 0.1 (3) and 11.8 (3)°, respectively, in one arm, and 4.6 (3) and -11.5 (3)° in the other]. In the crystal structure, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962238PMC
http://dx.doi.org/10.1107/S1600536808023556DOI Listing

Publication Analysis

Top Keywords

oriented dihedral
8
trimethoxy-phenyl rings
8
hydrogen bonds
8
33'-bis345-trimethoxy-benzo-yl-11'-o-phenyl-enedithio-urea ethanol
4
ethanol solvate
4
solvate mol-ecule
4
mol-ecule title
4
title compound
4
compound c28h30n4o8s2·c2h6o
4
c28h30n4o8s2·c2h6o benzene
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!