catena-Poly[[(nitrato-κO,O')silver(I)]-μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P'].

Acta Crystallogr Sect E Struct Rep Online

Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

Published: July 2008

In the title chain compound, [Ag(NO(3))(C(26)H(24)P(2))](n), the bis-(diphenyl-phosphino)ethane (dppe) units link the Ag(+) ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C-C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetra-hedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961910PMC
http://dx.doi.org/10.1107/S1600536808019442DOI Listing

Publication Analysis

Top Keywords

nitrate anion
8
catena-poly[[nitrato-κoo'silveri]-μ-12-bis-diphenyl-phosphinoethane-κpp'] title
4
title chain
4
chain compound
4
compound [agno3c26h24p2]n
4
[agno3c26h24p2]n bis-diphenyl-phosphinoethane
4
bis-diphenyl-phosphinoethane dppe
4
dppe units
4
units link
4
link ag+
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!