In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu-Cl coordinative bonds complementing four Cu-O bonds from two 2,4-dichloro-6-formyl-phenolate ligands in a distorted square plane. π-π stacking inter-actions are also formed between neighbouring aromatic rings, with a centroid-centroid separation of 3.624 (2) Å.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961934 | PMC |
| http://dx.doi.org/10.1107/S1600536808020424 | DOI Listing |
Publication Analysis
Top Keywords
catena-poly[copperii-bisμ-24-dichloro-6-formyl-phenolato-κoo'clκcloo'] title
4
title compound
4
compound [cuc7h3cl2o22]n
4
[cuc7h3cl2o22]n cuii
4
cuii atom
4
atom lies
4
lies centre
4
centre inversion
4
inversion adopts
4
adopts [4+2]
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!