The 1,3-benzodioxole ring systems in the title compound, C(22)H(22)O(8), are almost planar. The perhydro-furofuranyl system linking them adopts a distorted double-envelope conformation. Supra-molecular aggregation is effected by C-H⋯O, C-H⋯π and π-π [centroid-centroid distance of 3.755 Å, inter-planar distance of 3.633 Å and dihedral angle of 14.6°] inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961785PMC
http://dx.doi.org/10.1107/S1600536808018138DOI Listing

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