In the cation of the title compound, [Ni(C(3)H(4)N(2))(6)](C(7)H(3)Br(2)O(2))(2)·2C(3)H(7)NO, the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted octa-hedral environment by six N atoms from six imidazole ligands. In the crystal structure, cations, anions and solvent mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds into one-dimensional chains along [010]. In addition, the crystal structure is stabilized by weak C-H⋯O and C-H⋯N hydrogen bonds.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961690 | PMC |
| http://dx.doi.org/10.1107/S1600536808018989 | DOI Listing |
Publication Analysis
Top Keywords
crystal structure
8
hydrogen bonds
8
hexakis1h-imidazole-κnnickelii bis-24-dibromo-6-formyl-phenolate
4
bis-24-dibromo-6-formyl-phenolate nn-dimethyl-formamide
4
nn-dimethyl-formamide disolvate
4
disolvate cation
4
cation title
4
title compound
4
compound [nic3h4n26]c7h3br2o22·2c3h7no
4
[nic3h4n26]c7h3br2o22·2c3h7no niii
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!