The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol-ecule forms two hydrogen bonds to the 15-crown-5 mol-ecule, which is disordered about a center of inversion.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961118PMC
http://dx.doi.org/10.1107/S1600536808011070DOI Listing

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