AI Article Synopsis
- The compound features a symmetrical structure made up of two half-molecules that align at a center of symmetry.
- Thiol-ate groups connect the two molybdenum (Mo) atoms, giving the compound a quasi-octahedral geometry.
- Within this octahedral arrangement, the two sulfur (S) atoms are positioned in a cis configuration.
Article Abstract
The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol-ecules, each molecule lying on a centre of symmetry. The thiol-ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa-hedral geometry. In the octa-hedral environment the two ligating S atoms are in a cis arrangement.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961228 | PMC |
| http://dx.doi.org/10.1107/S1600536808010751 | DOI Listing |
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